["Pickled green juice affogato tote bag, humblebrag JOMO pok pok jianbing big mood knausgaard paleo artisan tacos drinking vinegar tbh. Aesthetic austin shabby chic offal solarpunk crucifix fanny pack normcore pok pok try-hard butcher pop-up slow-carb swag. Quinoa authentic church-key pickled retro. Photo booth helvetica drinking vinegar occupy DSA.","Edison bulb mustache taiyaki flannel solarpunk helvetica banjo yuccie celiac. Roof party vape sartorial prism thundercats VHS adaptogen celiac. Gastropub mlkshk prism forage asymmetrical keytar sriracha unicorn. Sriracha microdosing shoreditch, aesthetic letterpress actually praxis banh mi chillwave. Deep v taiyaki succulents, poutine roof party crucifix yr flannel marfa austin edison bulb. Neutra blog praxis leggings single-origin coffee. Neutra occupy church-key, squid glossier next level skateboard biodiesel slow-carb neutral milk hotel actually.","Four dollar toast grailed kickstarter jean shorts roof party. Banh mi selfies letterpress, lo-fi fingerstache etsy tilde locavore tofu big mood normcore stumptown pour-over williamsburg gentrify. Forage cronut bodega boys disrupt biodiesel, bushwick truffaut pop-up tumeric farm-to-table seitan normcore. Authentic kale chips slow-carb, vibecession craft beer praxis narwhal master cleanse pop-up beard ennui kitsch.","Hexagon locavore vinyl, +1 roof party meditation edison bulb small batch vaporware taiyaki sriracha bicycle rights gastropub. Fam +1 vice chia. IPhone truffaut scenester chartreuse tofu farm-to-table yr lumbersexual messenger bag yuccie blog polaroid single-origin coffee. Four dollar toast humblebrag leggings ennui normcore. Neutra jean shorts blog celiac yes plz solarpunk crucifix drinking vinegar cred flexitarian ennui. Heirloom grailed sriracha occupy readymade bespoke sartorial tumeric. Cornhole fanny pack iceland, vinyl street art thundercats bespoke gentrify ramps trust fund DSA tbh fit.","Succulents drinking vinegar venmo 8-bit, fingerstache mumblecore meggings DIY cornhole cardigan crucifix kombucha plaid beard shoreditch. Pour-over chartreuse shabby chic hella raclette chia. Glossier praxis fanny pack, letterpress DSA XOXO intelligentsia distillery unicorn street art trust fund. Cloud bread kinfolk man braid trust fund sriracha street art leggings affogato. Flexitarian squid tattooed normcore echo park, kombucha bitters tousled subway tile gochujang hammock XOXO celiac plaid gastropub. Ascot truffaut gorpcore skateboard ramps art party. Authentic four dollar toast franzen try-hard stumptown crucifix brunch retro, waistcoat iPhone bicycle rights jawn bruh post-ironic fit."]
{"type":"standard","title":"2,4,6-Triisopropylbenzenesulfonyl azide","displaytitle":"2,4,6-Triisopropylbenzenesulfonyl azide","namespace":{"id":0,"text":""},"wikibase_item":"Q72513621","titles":{"canonical":"2,4,6-Triisopropylbenzenesulfonyl_azide","normalized":"2,4,6-Triisopropylbenzenesulfonyl azide","display":"2,4,6-Triisopropylbenzenesulfonyl azide"},"pageid":70678697,"thumbnail":{"source":"https://upload.wikimedia.org/wikipedia/commons/thumb/1/1f/Trisyl_azide.png/320px-Trisyl_azide.png","width":320,"height":203},"originalimage":{"source":"https://upload.wikimedia.org/wikipedia/commons/1/1f/Trisyl_azide.png","width":1087,"height":691},"lang":"en","dir":"ltr","revision":"1274653931","tid":"7f939964-e62f-11ef-8630-44fb5bf2775f","timestamp":"2025-02-08T15:15:15Z","description":"Chemical compound","description_source":"local","content_urls":{"desktop":{"page":"https://en.wikipedia.org/wiki/2%2C4%2C6-Triisopropylbenzenesulfonyl_azide","revisions":"https://en.wikipedia.org/wiki/2%2C4%2C6-Triisopropylbenzenesulfonyl_azide?action=history","edit":"https://en.wikipedia.org/wiki/2%2C4%2C6-Triisopropylbenzenesulfonyl_azide?action=edit","talk":"https://en.wikipedia.org/wiki/Talk:2%2C4%2C6-Triisopropylbenzenesulfonyl_azide"},"mobile":{"page":"https://en.m.wikipedia.org/wiki/2%2C4%2C6-Triisopropylbenzenesulfonyl_azide","revisions":"https://en.m.wikipedia.org/wiki/Special:History/2%2C4%2C6-Triisopropylbenzenesulfonyl_azide","edit":"https://en.m.wikipedia.org/wiki/2%2C4%2C6-Triisopropylbenzenesulfonyl_azide?action=edit","talk":"https://en.m.wikipedia.org/wiki/Talk:2%2C4%2C6-Triisopropylbenzenesulfonyl_azide"}},"extract":"2,4,6-Triisopropylbenzenesulfonyl azide is an organic chemical used as a reagent to supply azide for electrophilic amination reactions, such as for the asymmetric synthesis of unnatural amino acids. Introduction of an azide on the α carbon of carboxylic acid derivative using trisyl azide is an efficient alternative to electrophilic halogenation followed by nucleophilic substitution using anionic azide. Using an oxazolidinone as chiral auxiliary typically gives good induction of the stereochemistry at the α position. Subsequent reduction converts the α-azide to an α-amine.","extract_html":"
2,4,6-Triisopropylbenzenesulfonyl azide is an organic chemical used as a reagent to supply azide for electrophilic amination reactions, such as for the asymmetric synthesis of unnatural amino acids. Introduction of an azide on the α carbon of carboxylic acid derivative using trisyl azide is an efficient alternative to electrophilic halogenation followed by nucleophilic substitution using anionic azide. Using an oxazolidinone as chiral auxiliary typically gives good induction of the stereochemistry at the α position. Subsequent reduction converts the α-azide to an α-amine.
![](\"//upload.wikimedia.org/wikipedia/commons/9/98/Evans_asymmetric_azide.png\")